20nmon
10th May 2009 - 03:31 AM
What is the current photovoltaic standard for number of electrons released per photon (if there is such a number)? Thanks in advance
rpenner
10th May 2009 - 04:39 AM
Since electrical energy efficiency is typically 15-25% for conventional materials, quantum efficiency (which can vary wildly by frequency) must peak between 40-100%. Calculations show that the actual range is more like 40-90% and 80-90% should be a design goal.
http://books.google.com/books?id=s5NN34HLWO8C
Enthalpy
12th May 2009 - 05:34 PM
Quantum efficiency (electron per photon) tends to be close to 100%. Power wastes have other causes:
- Photons with too little energy are not converted, but extra energy is wasted. Pity as Solar light has a wide spectrum.
- The output current is available at the direct voltage of a junction, and this voltage is quite lower than the bandgap of the semiconductor, though the bandgap determines the minimum photon energy. Example: 1.12eV photons minimum, but 0.5V direct voltage.
These two causes account for nearly all losses - and sadly, not much can be done against with a given semiconductor. Add a bit of quantum efficiency, parasitic reflection... and you get the usual figures.
20nmon
15th May 2009 - 01:22 AM
Thanks guys. I am guessing the shorter wavelengths would be more effective at giving the electrons and holes a head start?
Enthalpy
21st May 2009 - 01:48 AM
As soon as photons' energy exceeds somewhat one bandgap, they are very efficient at creating pairs, even in indirect-bandgap materials like silicon. More photon energy is just wasted.
Very nice site:
http://www.ioffe.ru/SVA/NSM/Semicond/One the 6th diagram of page
http://www.ioffe.ru/SVA/NSM/Semicond/Si/optic.htmlwhich is here when clicking to maximize
http://www.ioffe.ru/SVA/NSM/Semicond/Si/Figs/145.gifyou see a sharp transition at 1.12eV, indicating pair production.
The second transition is the direct gap of silicon.
20nmon
2nd July 2009 - 12:31 PM
I noticed the 5 eV and 10 eV absorption coefficent are very similar, but what happens for the 10 eV vs 5 eV photon? Where does the extra 5 eV go?
20nmon
3rd July 2009 - 06:36 AM
QUOTE (20nmon+Jul 2 2009, 12:31 PM)
I noticed the 5 eV and 10 eV absorption coefficent are very similar, but what happens for the 10 eV vs 5 eV photon? Where does the extra 5 eV go?
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