By Magnetar
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Polar ice caps, global weather and climate, ozone, and CO2 affect each other. Holes
in the ozone layer trigger a complicated, and not fully understood, series of events. Excess water vapor is mostly responsible. Methane, CO2, and hydrochloroflourocarbons (HCFC) are also to blame.
When water vapor rises into ozone-rich stratosphere over the Poles, UV can split H2O, leaving an HO+. This reacts with ozone, depleting it for a season. And, CFHCs compounds this issue.
With ozone holes, heat escapes to space, and the atmosphere below sinks. O2 has less chance to migrate upwards to repare the ozone. This is somehow connected to the global wind currents. Those wind patterns influence the oscilations of a "polar vortex" that normally is seasonal. With less ozone aloft, the patterns prolong the southern vortex, for example.
This, in turn, insulates and isolates Antarctica. It gets colder, as does everything above. Hence, less O2 rises to replenish the ozone. Not only is the southern polar vortex less variable, but world patterns are effected. Through "global warming", the northern hemisphere warms faster than the southern hemisphere. This leads to more southern winds, and a warmer ocean. Instead of the cool ocean absorbing CO2, the winds stir up the lower depths, which churns up CO2 and saturates it to the surface. This prevents sinking and uptake of new CO2 from the atmosphere.
So, less manmade CO2 goes into the ocean, and instead, is carried aloft. Along with various destructive gases, CO2 is suspected of enabling additional water vapor to move upward, which might harm ozone. General altitude- 15-35 km, and avg. temp 300* K (80*F, 27*C).
CO2 is disolved into the ocean to form carbonic acid, H2CO3, which disolves into carbonate and bicarbonate. The carbonate is removed from solution ( eg. as CaCO2), while the bicarbonate (2HCO3-) reacts to form =>H2CO3 + CO3. Most of this inorganic carbon in the ocean exists as bicarbonate (~88%), along with carbonate ions (11%) and CO2. The co-existence of these species in seawater creates a chemical buffer system, regulating the pH and the pCO2 of the oceans.
We read that rather than merely sinking or convecting down near the colder polar oceans, surface waters in both hemispheres are also on a conveyor belt system. They occasionally outcrop along the way, with less saturated lower layers rising to absorb additional CO2 (or even out-gas in warmer climes). The news lately has been that climate warming melts freshwater ice at the poles, which lowers the density of those surface waters. That diminishes the sinking of colder water at the surface, and the uptake and transport of CO2 from the polar climes.
And, Dreaming_awake mentioned that sea creatures absorb calcium, live/reproduce/die natural cycles, and sink away exposed skeletal material. It reacts with CO2, confining it downward, as well. So, that adds another long term sink for CO2. Provided, ocean pH (read pCO2) is WNL.
This leads to a system of storage of CO2 in oceans, beginning with high latitudes, where cold water conveys downward.
But, new research concludes pCO2 is currently at a high saturation point in the Southern Ocean. Not so much from dilution of saltwater by meltwater leading to transport slowdown (I'm not clear on that), but from the weather patterns that lead to increased winds. And, it relates back to the ozone holes, which are not due to repair themselves for several more decades. (China used lots of freon since 1990, and only just shut down production).
MSN news- quote
“This is the first time that we’ve been able to say that climate change itself is responsible for the saturation of the Southern Ocean sink. This is serious. All climate models predict that this kind of ‘feedback’ will continue and intensify during this century. The Earth’s carbon sinks – of which the Southern Ocean accounts for 15% – absorb about half of all human carbon emissions. With the Southern Ocean reaching its saturation point more CO2 will stay in our atmosphere.”
This new research suggests that stabilisation of atmospheric CO2 is even more difficult to achieve than previously thought. Additionally, acidification in the Southern Ocean is likely to reach dangerous levels earlier than the projected date of 2050.
Professor Chris Rapley, Director of British Antarctic Survey said, “Since the beginning of the industrial revolution the world’s oceans have absorbed about a quarter of the 500 gigatons of carbon emitted into the atmosphere by humans. The possibility that in a warmer world the Southern Ocean – the strongest ocean sink - is weakening is a cause for concern.”
The saturation of the Southern Ocean was revealed by scrutinising observations of atmospheric CO2 from 40 stations around the world. Since 1981 the Southern Ocean sink ceased to increase, whereas CO2 emissions increased by 40%. End Quote
Abstract (subscription)-
Based on observed atmospheric CO2 concentration and an inverse method, we estimate that the Southern Ocean sink of CO2 has weakened between 1981 and 2004 by 0.08 PgC/y per decade relative to the trend expected from the large increase in atmospheric CO2. This weakening is attributed to the observed increase in Southern Ocean winds resulting from human activities and projected to continue in the future. Consequences include a reduction in the efficiency of the Southern Ocean sink of CO2 in the short term (~25 years) and possibly a higher level of stabilization of atmospheric CO2 on a multicentury time scale.
http://www.ncbi.nlm.nih.gov/sites/entrez?c...t_uids=17510327"