rpenner
30th September 2009 - 01:58 PM
He shouldn't have said Celsius, He should have said Rankine or Kelvin, with a zero at the Absolute Zero, where the ideal gas volume is also zero.
http://en.wikipedia.org/wiki/Rankine_scaleLikewise gauge pressures must be converted to absolute pressures.
So the though process for the first problem looks like this:
PV = NRT So...
R = PV/NT = P₁V₁/N₁T₁ = P₂V₂/N₂T₂
V₁ = V₂ (given)
N₁ = N₂ (because no gas enters or exits)
So
P₁/T₁ = P₂/T₂ (for constant V and N given the ideal gas law)
So P₂ = P₁T₂/T₁
And P(absolute) = p(gauge) + P(atmospheric pressure), and T(Absolute) = t(℉) + 459.67°R
So we get
p₂(gauge) + P(atmospheric pressure) = (p₁(gauge) + P(atmospheric pressure)) (t₂(℉) + 459.67°R)/(t₁(℉) + 459.67°R)
or
p₂(gauge) = (p₁(gauge) + P(atmospheric pressure)) (t₂(℉) + 459.67°R)/(t₁(℉) + 459.67°R) - P(atmospheric pressure)
So we can look up P(atmospheric pressure) = 14.7 psi and calculate this.
So the first calculation (expressed in psi gauge but using intermediates of absolute pressure in psi and absolute temperature in Rankine) looks like this:
http://www.google.com/search?q=what+is+(32...%2B459.67)-14.7As a side note, Google's calculator looks smart, but is not perfect, so this also works, even though it looks misleading because of the silent conversion to absolute temperatures:
http://www.google.com/search?q=what+is+(32...scals+in+psi%3F