rpenner
28th August 2009 - 04:12 AM
It's about information, not just temperature.
Take a box of atoms. At low energies (quantum effect) the box can only be in a finite basis of states (like my lower-case base-16) string. At high energies, the box can be in a much larger number of states (like my base-64 string).
To the macroscopic observer all these states look the same -- they all have about the same energy. So the equilibrium box has more possibilities -- and more entropy. Also there are many, many more states available to the box at higher temperature. (It's this number of indistinguishable states which is close to the information theory definition of information entropy.)
Now cut the box into two. How much entropy does each half have? Each half has half the entropy.
Now cool one box off to the low temperature, and it has half the entropy of the whole box,
when the box was at low temperature.
So now we can see why a box half-high and half-low has less entropy than the same box at equilibrium. All the energy that flows to the low temperature side increases the entropy of the cold side faster than it decreases the entropy of the warm side. In fact, the entropy change for a small amount of energy is proportional to 1/T and proportional to the amount of energy.
QUOTE
δS = δE/T