And suddenly my motivation for
trying to discuss this, and inject some 'rationality' into the conversation.
Once again, YOU RC are heading, once again, down the road of "You've been indoctrinated into the cult of science, you only know the textbooks, therefore everything you know is wrong", and frankly it's bugging the heck out of me.
The fact that I may be able to quote things chapter and verse from textbooks is a reflection of the
depth of my understanding of chemistry and chemical processes.
My intrest is in
APPLIED chemistry, not
PURE chemistry, as you seem to be implying.
The fact that I have in my lap while I type this the course material for the postgrad paper I am doing this semester that deals with things such as chemical weapons of mass destruction, and how to deal with them should they be released into the environment should tell you something.
I have been discussing things in this thread in GOOD FAITH.
Right now, you are showing very BAD FAITH RC, and I am NOT impressed.
Once again, you are demonstrating that you are unwilling to listen to someone who actually knows what they're talking about on the subject, apparently preferring to believe whatever is convenient.
First point: You are, and have been adovacting Furnace like conditions in the floors, the heat held in the steel and the concrete of the walls and floor doesn't simply 'vanish' the hot air doesn't simply vanish, it doesn't work that way. You can't invoke furnace like conditions for part of the scenario, and then have them 'vanish' when it's convenient. The comment in relation to the photo is that it was taken between the impact and the collapse, and it was taken early, rather then late in the footage. Also, it's in the
first tower to stand, which survived 55 minutes between the impact and collapse.
Second point: Close inspection of the impact footage reveals three flashes when the aircraft strikes the cladding, the three flashes are when the three densest parts of the aircraft strike the cladding. These flashes are the Al powder generated by the impact igniting.
Third point: Heating due to friction would be extremely localized, and it's obvious from the footage that the plane did not (appear) to slow down significantly as it entered the building, so it's fairly safe to assume that most of the impact energy would have been released in the impacts with the central columns.
Fourth point: Combustion of Hydrocarbons does not release super heated steam, it releases water in the gas phase. Steam is water in the liquid phase (in very small droplets). This is why it's possible to superheat it, and before you go and try and contradict this point, take a careful look at pictures of steam being vented at Geothermal plants, there is a space between the steam and the nozzle, in this space, water exists in the gas phase.
Fifth point: I don't have the data at my fingertips right at this instant, and to be honest, given the responses I have received, I'm feeling far from motivated to go and look it up, but you're assigning much higher explosion velocities to the fireball then 1. Are generally observed in comparable fireballs, and 2. Were observed in this particular fireball.
Sixth point: Did I, or did I not explicitly state, or at least imply in one of my posts to chainsaw about his experiments that there is/was the posibility for small scale localized thermite reactions.
Seventh point: I'm aware of the reactions between Aluminium and Silicates.
Eighth point: I'm feeling to lazy to go and look up the thermochemical data on Aluminium carbide and it's reactions, I may do it later, but there's something that seems not quite right about what you've said in that respect - but i'm not able to put my finger on it right now.
Ninth point: Most of what you say about the Carbon or what ever swamping any light or effects from whatever explosions, is, IMO, bogus. One of the aircraft effectively occupied a corner of the building, some fragments even exited IIRC, this means that all of the effects that you are claiming should have been noticable, but, nothing.
10th point: I'm not sure how to address what you 'claim' wrt the splattering/flowing Aluminium, again, there's something in there that strikes me as being wrong, but i can't quite put my finger on it.
11th point: I don't think that the aqueous processes you're talking about are as important as you seem to think they are. Agaom, there seems to me to be something inherently wrong with some of those things, but I can'r put my finger on it.
Question.
Where's the information? It's not that hard to find. Take the PVC discussion, what use is all this discussion about HCl, if you don't know how fast it's generated, and you don't know how much was generated.
I've already pointed out some of the potential problems with the experiments chainsaw's doing, and I get criticized for doing this? What's the deal with that? How is Chainsaw supposed to conduct
better experiments to prove his point my reliably and more emphaticaly, if nobody points out the (potential) problems in his experiments? (Or anyone elses experiments). You know? You're so quick to jump on the 'thinking outside the box' bandwagon that you manage to completely overlook the simple, obvious truths.
And you overlook the obvious questions:
Why is it that the tower that took the most glancing blow fell first?
Why is it that the tower with the shortest lived fires fell first?
I can offer explanations for both of those without invoking exotic chemistry, but, if the fire was responsible, then the other tower should have collapsed first. It really is that simple.
I have other observations I can offer, but I find myself asking it is really worth it? Because so far, nobody (except maybe Arthur, and one or two others) actually seems interested in having a seriouse and rational discussion.
Trippy calm down, you proposed problems with an experiment that you did not understand I was not critizing you, You simply did not know what the objective of the experiment was.
You believed it was a thermite spark, which it was but it was inside the oxide layer from an inclusion of Fe 304. not from the rust on the skillet but from a planned event with in the oxide layer.
The other pictures were of Aluminum oxidizing because of wave action induced by sound disrupting the bonds of the oxide on the Aluminum.
As for water in the gas phase, it is still reactive to metals, it is still H2O.
http://pubs.acs.org/cgi-bin/abstract.cgi/o.../om9810504.htmlhttp://links.jstor.org/sici?sici=0080-4630...%3E2.0.CO%3B2-KIn fact the best reactant possible is a recycling hydrogen flame, trapped under a layer of steel.
I also need to point out that the part of the plane you mentioned was near a window and not engulfed in a fireball soot or smoke.
To claim it negates anything is bogus in itself.
QUOTE
Ninth point: Most of what you say about the Carbon or what ever swamping any light or effects from whatever explosions, is, IMO, bogus. One of the aircraft effectively occupied a corner of the building, some fragments even exited IIRC, this means that all of the effects that you are claiming should have been noticable, but, nothing.
QUOTE (->
| QUOTE |
| Ninth point: Most of what you say about the Carbon or what ever swamping any light or effects from whatever explosions, is, IMO, bogus. One of the aircraft effectively occupied a corner of the building, some fragments even exited IIRC, this means that all of the effects that you are claiming should have been noticable, but, nothing. |
First point: You are, and have been adovacting Furnace like conditions in the floors, the heat held in the steel and the concrete of the walls and floor doesn't simply 'vanish' the hot air doesn't simply vanish, it doesn't work that way. You can't invoke furnace like conditions for part of the scenario, and then have them 'vanish' when it's convenient. The comment in relation to the photo is that it was taken between the impact and the collapse, and it was taken early, rather then late in the footage. Also, it's in the
first tower to stand, which survived 55 minutes between the impact and collapse.
Than Trippy I should point out that the conditions would not be evident much past the initial impact other than on the underside of the upper floor where heat dissipation in air would occur.
BY your statement I should be fried when ever I use my cutting torch, my oxygen lance, or perform experiments like this.

The experiment involved compressed air blown though a torch head, onto steel with a burning piece of Cannel Coal under it. The compressed air, heated the coal to the point that the steel itself burned, resulting in hot iron oxide reacting with the carbon in the coal and all the intense heat and sparking.
It is the same process that creates steel in the first place from Iron ore.
Chainsaw,
19th July 2007 - 03:19 PM
QUOTE (adoucette+Jul 19 2007, 02:17 PM)
Please, continue with your experiments. I find your willingness to put ideas to the test very commendable, just, as I said before, do so safely.
I will say that I have learned, that when I'm working in an area where I'm not an expert and I find something that APPEARS to contradict the experts in the field that it is usually not the experts who are wrong.
Keep this in mind when you compare what you find out with what the experts in the field say. Its NOT that the experts can't be wrong, its just that they aren't that often, and particularly on KEY aspects of their specialty.
For example, lets say you are right and the thermal energy released at impact from chemical reactions was 1/3 greater than NIST thought, that STILL wouldn't make NIST's overall conclusions wrong, since that would still be so little of the total energy released during the fires.
Still, even if additional chemical energy may not significantly affect the overall conclusions that NIST arrived at, it COULD explain things like the spericals, so by all means, continue your investigation into the chemical nature of the fires. But DO try to start quantifying the amount of energy released and then compare it to the 8,500 GJ of energy that was released by the fire before assuming you have found a source of additional energy large enough to affect NIST's conclusions.
As an aside, I think that the reason many people underestimate the sheer magnitude of the fires is because of the scale of the buildings. One floor of the WTC had an area ~ equal to the playing area of a football field and was loaded with over 125,000 lbs of combustible material. Imagine fires raging on 6 or so of those huge floors and you start to get the idea of how massive the WTC fires were.
Consider what 8,500 Gigajoules of energy from the fires represents. Its equal to ALL the energy (and then some) that two LARGE Nuclear power plants could produce over the same time the fire was burning.
So the point is, unless you come up with an energy source GREATER than ~800 Gigajoules, then it would easily fit within the error bars of NIST's Impact models, Fire Dynamics Simulator and the Fire Structure Interface.
So IF you DID find an unaccounted for energy source even half that size, even though it wouldn't invalidate NIST, it WOULD be an exciting find, and might very well help explain some of the mysteries that still remain, so by all means keep looking, experimenting and questioning.
All I ask is that you don't PRESUME to have found that NIST made a significant error, or "fudged the model" etc without presenting quantifiable evidence to support that position.
Arthur
The problem Arthur is I am getting to many reactions to fast with just a small added amount of energy in the impacts.
It is a very complex situation I do the large scale experiments then I have to break everything down into small scale tests so I can figure out what is happening.
A small change in impact energy generates a higher reaction rate and even more energy release in localized areas, such as the area of the buildings that Frank is referring too.
All the data from Nist, matches except at the first stages of the impact, and the later post collapse for which NIST gave no data.
Every expert I have contacted has said the same thing Read the NIST report, I have that is the problem.
I do not doubt that there are experts that know more than I do, one of them is Frank.
I just can not reconcile what they are telling me with what actually occurs, and with the physical evidence of the spiracles that Dr. Jones found.
What I have found is if the fire proofing was degraded to the point that NIST Claims the towers should have fallen even sooner than they did.
Like Frank I think that the fire proofing was not degraded to the degree claimed, I think the buildings would have fallen eventually anyway do to other Natural causes. Right conclusion, wrong method to collapse.
It is backed up by physical evidence that NIST did not address such as the burned cars and the sustained heating in the rubble piles.
I have also received input from PHDs. that work at the local Aluminum plant as metallurgists, and they are confirming much of what I have addressed here, they however do not want to comment publicly because of the 9/11 controversy and they do not want to risk being thought of as contributing to the Cters.
After all I do live near a town built on the Aluminum industry.
http://goliath.ecnext.com/coms2/gi_0199-95...maining-20.html I must also note that the experiments that have made me puzzled were conducted after the comment period had ended on the NIST report, so it was impossible for me to comment on something that I had not yet discovered, just as it was impossible for Frank to comment on his research for the same reason.
The experiments also Show why the core failed first, much Like RC. is explaining, and the whole thing could have been easily over looked.
I do not believe any more than 1/5th the total mass of the airplane was consumed in the impact, however that leads to a significant increase in thermal energy especially when the plane impacts the core, and thousands of super hot micro projectiles reflecting upward and downward though the elevator shafts.
I also note that the micro particles would do some damage to the fire proofing, but I am unsure how much they should simply pass though it.
I just feel that even though NIST is complete, that scientific research and discovery must continue.
adoucette
19th July 2007 - 03:45 PM
QUOTE (Chainsaw+)
What I have found is if the fire proofing was degraded to the point that NIST Claims the towers should have fallen even sooner than they did.
Keep in mind that that is the same thing NIST found. Their models were "hot" in that either they over-estimated the amount of fire-proofing that was degraded or they over estimated the amount of heat that was released (or a bit of both), because the models reached the point of collapse a bit faster than the actual towers did.
BUT, NIST was not trying to find a set of input parameters to their model that would EXACTLY match the temporal behavior of the towers. The models were used to ILLUSTRATE the LIKELY DAMAGE to the interior structure from the plane crash, the LIKELY growth, spread and intensity of the ensuing fires and then the most likely overall BEHAVIOR of the main structural components of the towers under the impact/fire conditions.
The MOST accurate model compared to reality was the first few hundreths of a second after the INITIAL impact, the model then becomes less and less accurate as TIME goes on. Its easy to see how just varying the speed of the plane a bit, the angle of impact a bit etc causes quite a significant variation in results. From that point on, the various model's error bands can ONLY expand.
Which is why the NIST scientists say they are dealing with the most PROBABLE scenario for the collapse. Consider that NIST is aware that ALL their model results have fairly large margins of error.
Now, back to your claim:
Specifically:
How much additional energy have you found?
What was the source of this additional energy?
Over what time frame was this energy released?
How much sooner do you estimate that each of the towers would have fallen when using NIST's estimate of SFRM damage and your estimate of additional energy?
Arthur
Chainsaw,
19th July 2007 - 05:28 PM
QUOTE (adoucette+Jul 19 2007, 03:45 PM)
QUOTE (Chainsaw+)
What I have found is if the fire proofing was degraded to the point that NIST Claims the towers should have fallen even sooner than they did.
Keep in mind that that is the same thing NIST found. Their models were "hot" in that either they over-estimated the amount of fire-proofing that was degraded or they over estimated the amount of heat that was released (or a bit of both), because the models reached the point of collapse a bit faster than the actual towers did.
BUT, NIST was not trying to find a set of input parameters to their model that would EXACTLY match the temporal behavior of the towers. The models were used to ILLUSTRATE the LIKELY DAMAGE to the interior structure from the plane crash, the LIKELY growth, spread and intensity of the ensuing fires and then the most likely overall BEHAVIOR of the main structural components of the towers under the impact/fire conditions.
The MOST accurate model compared to reality was the first few hundreths of a second after the INITIAL impact, the model then becomes less and less accurate as TIME goes on. Its easy to see how just varying the speed of the plane a bit, the angle of impact a bit etc causes quite a significant variation in results. From that point on, the various model's error bands can ONLY expand.
Which is why the NIST scientists say they are dealing with the most PROBABLE scenario for the collapse. Consider that NIST is aware that ALL their model results have fairly large margins of error.
Now, back to your claim:
Specifically:
How much additional energy have you found?
What was the source of this additional energy?
Over what time frame was this energy released?
How much sooner do you estimate that each of the towers would have fallen when using NIST's estimate of SFRM damage and your estimate of additional energy?
Arthur
Well as you said the initial impact energy of one third, equals ~100GJ I think however that is low for the thermal energy released by one fifth the planes aluminum, if more than one Fourth Oxidized, you would have a white super hot cloud as you indicated from what I have seen Carbon is good at absorbing the light a perfect black body radiation source, and Hydrocarbons vaporize faster absorbing heat as well this reduces the visible white light by absorbing it. The metal you refereed to as burning in the fire is near a window so that would be more noticeable.
I believe the energy would be closer to 3 GJ
That is not much but is enough to start and catalyze Neu's reaction, which reaches 50 GJ on the most effected area, the trusses, Other Reactions caused by Neu's reaction, such as reactions Catalyzed because of Aluminum Chloride and Chloride metal reactions would lead to an additional 20-30 Gj, Hydrogen reactions are hard to Quantify but could have added an additional 20 Gj.
So were looking at possibly and I must say Possibly 100-120 GJ of added energy, on the most effected areas, which would lead to about a 10- 20 minute error given Nists degree of fire proofing loss.
That might be within the error margin, of NIST, in fact I believe it is, the point is the fire proofing may not have had to have been degraded as much to cause the collapse.
One of the things that puzzled me about the NIST report is why it was so hot, they used video and other evidence to create the model, and with the fire proofing removed it was too hot.
The metals contain far more energy per weight than the Carbon based fuels, just most people believe they would always exhibit white light when burning, what I have found is,
One, the light can be absorbed and masked out.
Two, They can oxidize slowly over a large surface area and produce a gradual release that is still significant.
Three, They can recycle other compounds such as hydrogen that burns with an almost UN noticeable flame.
Just because you can not see a metal burning white does not mean it is not adding additional energy to the flame, a hydrogen flame is simply H20 in a low energy plasma form. It can react on metal surfaces, or inside of hollow metal tubes especially steel.
It think if I keep working on this even more energy can be found but the reactions are so hard to quantify, that it takes a long time to work them out. It is not something that is easy because every time I look I find something else that complicates the reactions such as the carbon-Iron-oxide reaction that could have provided more heat by recycling the oxygen from Neu's reaction.
I know it could have added aditional heat and probably the most additional heat, but I am finding it almost impossible to Quantify.
I wish that people as you say who are more trained, and smarter than I would look into these, However no one wishes to waste time on them or on Sept 11/2001, since the NIST report is complete.
I just wanted to find the source of the spheres, and I stumbled on to all this by accident, Like you I thought that they could be made simply by melting and that proved not to be the case, they are a result other reactions.
carterelliott
19th July 2007 - 05:29 PM
QUOTE
A small change in impact energy generates a higher reaction rate and even more energy release in localized areas, such as the area of the buildings that Frank is referring too.
QUOTE (->
| QUOTE |
| A small change in impact energy generates a higher reaction rate and even more energy release in localized areas, such as the area of the buildings that Frank is referring too. |
Its easy to see how just varying the speed of the plane a bit, the angle of impact a bit etc causes quite a significant variation in results.
Please note that these are two characteristics of *chaotic systems*, a point I tried to make in my first posts on this topic, some time back. (Maybe you'll remember my comment about how few fires look "boxy".)
It's a fundamental problem when attempting to characterize a chaotic system using linear assumptions.
adoucette
19th July 2007 - 05:52 PM
QUOTE (Chainsaw,+Jul 19 2007, 01:28 PM)
So were looking at possibly and I must say Possibly 100-120 GJ of added energy, on the most effected areas, which would lead to about a 10- 20 minute error given Nists degree of fire proofing loss.
That might be within the error margin, of NIST, in fact I believe it is, the point is the fire proofing may not have had to have been degraded as much to cause the collapse.
Except even 120 GJ is only 1.4% of the total energy released by normal combustion, so even if this energy had 5 times the effect on the structure as the energy released by the fire, it STILL would probably not alter the timeline by even 10 minutes.
So my point would be, if one was to assume you are right about the additional energy, it would have an insignificant impact on the timeline.
If you were to assume you are right about the additional energy and you further assumed the energy had a five-fold impact on the structural elements of the tower, it STILL would not have a significant impact on the timeline or the NIST conclusions.
On the other hand, IF you can substantiate the claims that there was this much additional chemical energy released during the event then it might explain some of the chemical features you are researching.
Arthur
NEU-FONZE
19th July 2007 - 06:41 PM
Arthur/Chainsaw:
Here is a simple calculation that illustrates the difference between generalized heating of a building vs. localized heating of a structure within the building:
Let's assume the fire in a WTC tower released 8000 GJ of heat and, (being very generous), also assume that ALL this heat was absorbed by the upper 15 floors having a total mass of 50,000 tonnes. In addition let's assume that the average heat capacity, Cp, of the building's structural materials was 1000 J/kg. The resultant temperature increase, Delta(T), is given by:
Delta(T) = [Total Heat Released] / [Mass x Cp]
= 8 x 10^12 / [50,000,000 x 1000] = 160 deg C
Now consider the case of 50 GJ of chemical reaction heat being delivered directly to the steel in the truss assemblies on one floor. The heat capacity of iron is about 500 J/kg and we shall take the mass of steel in the trusses on one floor as 75 tonnes. In this case:
Delta(T) = 50 x 10^9 / [75,000 x 500] = 1333 deg C
These numbers are, of course, very approximate but they do show that a little bit of LOCALIZED heating is much more effective than GENERALIZED heating and could easily heat a single building component to a temperature sufficient to melt steel.
Chainsaw,
19th July 2007 - 06:50 PM
QUOTE (adoucette+Jul 19 2007, 05:52 PM)
Except even 120 GJ is only 1.4% of the total energy released by normal combustion, so even if this energy had 5 times the effect on the structure as the energy released by the fire, it STILL would probably not alter the timeline by even 10 minutes.
So my point would be, if one was to assume you are right about the additional energy, it would have an insignificant impact on the timeline.
If you were to assume you are right about the additional energy and you further assumed the energy had a five-fold impact on the structural elements of the tower, it STILL would not have a significant impact on the timeline or the NIST conclusions.
On the other hand, IF you can substantiate the claims that there was this much additional chemical energy released during the event then it might explain some of the chemical features you are researching.
Arthur
That is the entire point, also the chemical reactions themselves also weaken and thin the trusses leading to a faster collapse by subtracting energy from them.
Any energy added from steel is subtracted from the strength of the building to resist collapse because the buildings support structure is itself fuel.
The energy is there it is just a matter of forming the reactions to convert it.
I also might add that of the total carbon combustion total of GJs most went out of the building as expanding gasses carbon dioxide and nitrogen along with other hot combustion byproducts, where this energy is mostly retained by the metals themselves because little vapor is created. Although air is expanded by the heating.
Also that Neu's reaction takes place in an Isolated and insulated location under a 4 inch concrete slam which would help insulate it, and trap the heat.
Thermal retention is more important than overall thermal release.
PhysOrg scientific forums are totally dedicated to science, physics, and technology. Besides topical forums such as nanotechnology, quantum physics, silicon and III-V technology, applied physics, materials, space and others, you can also join our news and publications discussions. We also provide an off-topic forum category. If you need specific help on a scientific problem or have a question related to physics or technology, visit the PhysOrg Forums. Here you’ll find experts from various fields online every day.
To quit out of "lo-fi" mode and return to the regular forums, please click
here.